Mystery Jets are also set to appear
Both bands will be spinning the discs at ‘LDN Calling’ with a host of stars including ‘T4’s Alexa Chung and Peaches Geldof at the Elbow Room in Islington.
The event kicks off this Friday (May 25) from 8pm and is free entry.
Babyshambles are currently putting the finishing touches to their forthcoming second album.
They are due to appear at Glastonbury, T In The Park and V Festival in the summer.